Impregnated capacitor

ABSTRACT

Electrical capacitors are impregnated with liquid dielectric compositions comprising mixed halogenated aliphatic-aromatic ethers.

[11] 3,745,432 1 July 10, 1973 United States Patent 1 Munch et a].

[56] References Cited UNITED STATES PATENTS IMPREGNATED CAPACITOR h H. Munch, Webster Groves,

[75] Inventors: Ralp l74/l7 LF 317/258 317/259 2,288,373 6/1942 3,025,440 3/1962 Martin 3,423,655 l/l969 Watchman.....................,....

Apr. 28, 1972 Primary Examiner-E. A. Goldberg 1 pp No 248 671 Att0rneyNeal E. Willis etal.

221 Filed:

[57] ABSTRACT Electrical capacitors are impregnated with liquid digi electric compositions comprising mixed halogenated 1e 0 arc I M/7 u; aliphatic aromafic ethem 3 Claims, 2 Drawing Figures PAIENIEBJUL 1 0191s 3 7 5,432

FIGJ. FIG.2.

IMPREGNATED CAPACITOR BACKGROUND OF INVENTION l. Field of Invention The present invention relates to capacitors of the type consisting of wound or stacked alternating conducting layers and dielectric layers enclosed in a sealed case, and to a liquid dielectric composition suitable for impregnating such capacitors.

2. Description of Prior Art A common type of electrical capacitor comprises a combination of spaced metal foil conductors having interposed therebetween a dielectric sheet which may be paper, polymeric film or a combination of paper and polymeric film. The dielectric sheet material and the interstices within the dielectric sheet and between the dielectric sheet and the conductors are impregnated with a liquid dielectric composition. Such impregnation is essential in order to realize the greatest dielectric strength of the dielectric material.

The preferred dielectric composition for impregnating capacitors has heretofore been polychlorinated biphenyl which has a relatively high dielectric constant and good low temperature properties. Certain of the polychlorinated biphenyls however, have now beendiscovered to be resistant to natural degradation and, when released into the environment, these materials may enter the life cycle and be potentially harmful to ecology. Even though capacitors are sealed units and escape of the impregnant into the environment can be prevented to a large degree, it has nevertheless become desirable to provide an alternate composition for impregnating capacitors which does not contain potentially harmful polychlorinated biphenyls.

It is accordingly an object of the present invention to provide a novel dielectric fluid composition for impregnating electrical capacitors which is free of polychlorinated biphenyls. It is a further object of this invention to provide capacitors containing said novel dielectric fluid composition. Other objects of this invention will be apparent from the ensuing description and claims.

SUMMARY The compositions of the present invention which are useful as impregnants for capacitors of the type having alternate layers of a metal foil conductor and a sheet of solid dielectric material comprise mixed halogenated aliphaticaromatic ethers represented by the structure wherein R is an alkyl of from one to about 10 carbon atoms, each X is individually chlorine, fluorine or bromine, and n is l or 2. in addition, the dielectric impregnant may comprise a mixture of such compounds, and such mixtures are particularly preferred where the individual compounds have high melting points and mixtures have appreciably lower melting points.

Capacitors containing said compositions may be constructed and impregnated according to standard procedures. The dielectric sheet material interposed between the metal foil conductors may be paper, polymeric film such as polypropylene, or a combination of paper and film. Such capacitors impregnated with the compositions of the present invention are characterized by a low dissipation factor, high dielectric constant and good life test performance.

DESCRIPTION OF DRAWINGS FIG. 1 is a perspective view of a partially uncoiled convolutely wound capacitor.

FIG. 2 shows a fully assembled capacitor of the type shown in FIG. 1 and a dielectric fluid impregnant.

DESCRIPTION OF PREFERRED EMBODIMENTS The dielectric liquids of the present invention preferably comprise a major proportion, i.e., at least about percent by weight, of one or more mixed halogenated aliphatic-aromatic ethers represented by the structure wherein R is an alkyl of from one to about 10, and preferably from about three to eight carbon atoms, each X is individually chlorine, fluorine or bromine, and n is l or 2. Particularly preferred ethers are those where R is n-propyl, isopropyl, n-butyl, or isobutyl.

Illustrative of specific preferred mixed ethers are nbutyl-o-chlorophenyl ether, n-butyl-o-bromophenyl ether, n-butyl-o-fluorophenyl ether, n-butyl-2, 4- dichlorophenyl ether, n-butyl-2,4-dibromophenyl ether, n-butyl-2,4-difluorophenyl ether, and mixtures thereof, particularly mixtures of n-butyl-ochlorophenyl ether and n-butyl-2,4-dichlorophenyl ether in a ratio of from about 1:4 to about 4:1.

In addition to the mixed ether compounds, the dielectric liquids of this invention may contain up to about 30 percent by weight of a diluent or solvent. The employment of such diluents is particularly desirable where the mixed ether has a melting point above about 0 C. and low temperature performance can be improved through the use of a diluent.

Diluents useful in the dielectric compositions of the present invention are preferably hydrocarbons and hydrocarbon ethers including alkanes of about 12 to 20 carbon atoms, alkyl benzene, alkyl naphthalene, alkyl biphenyl, alkyl polyphenyl, alkylaryl ethers and alkyl substituted derivatives thereof, diaryl alkanes and alkyl substituted derivatives thereof, and diaryl ethers and alkyl substituted derivatives thereof, wherein said alkyl groups and alkanes have from one to about 20 carbon atoms, said aryl radicals are benzene, naphthalene, biphenyl, or polyphenyl, and said polyphenyls include from three to about five phenyl groups.

Specific examples illustrative of such organic diluents bilizer in the system is to neutralize certain ionizable contaminants or extraneous materials which may be present or which may be formed in the system. Such contaminants may include residual catalyst or catalyst activators which remain from resin forming reactions. Contaminants may also include degradation products caused by environmental or voltage induced chemical reaction in the system. These undesirable contaminants and extraneous products have an adverse effect on the dissipation or power factor of the impregnated dielectric system, and stabilizing agents have been found to be highly effective in maintaining a low power factor in impregnated dielectric systems.

Examples of particularly preferred stabilizing agents are epoxides such as l-epoxyethyl-3 ,4- epoxycyclohexane, 3 ,4-epoxycyclohexylmethyl-3 ,4- epoxycyclohexane carboxylate, 3,4-epoxy-6- methylcyclo hexylmeth yl-3 ,4-epoxy-6- methylcyclohexane carboxylate, and the like. These stabilizers are preferably employed in the dielectric fluid compositions of this invention in amounts in the general range of from 0.001 to about 8 percent by weight, and more preferably from about 0.1 to 3.0 percent by weight.

The dielectric sheet materials interposed between the conductors in the capacitor and impregnated with the dielectric fluid compositions of this invention may be comprised of a solid flexible porous material such as highly refined cellulose paper, or of a substantially nonporous polymeric film material such as a polyolefin, or of a combination of paper and polymeric film. The paper material is preferably two or more sheets of Kraft capacitor paper having an individual sheet thickness of from about 0.3 to 2.0 mils, and preferably from about 0.6 to 1.0 mils, with a total combined thickness suitable for the design voltage of the capacitor. Such paper has a dielectric strength which is relatively good as compared to other dielectrics and has a relatively high dielectric constant. The polymeric material is preferably biaxially oriented polypropylene film although other members of the polyolefin family, particularly polyethylene and 4-methylpentene-l have found some use in capacitor applications. Other useful polymeric materials include polyesters, polycarbonates, polyvinylidene fluoride, and polysulfone. Although either paper or polymeric film may be used alone, combinations of both are often used. The paper is positioned adjacent the polymeric film to function as a wick to pass the dielectric liquid impregnant into the area coextensive with the area of contact between the porous paper and the substantially nonporous polymeric material.

Capacitor devices employing the present invention may have the general structure and configuration as shown in FIG. I which is a convolutely wound capacitor 10 comprising separate electrodes or armatures 11 and 12 and intermediate dielectric spacers l3 and 14. Terminal connectors 15 and 16 have enlarged surfaces (not shown) in contact with electrodes 1 1 and 12. Electrodes 11 and 12 may comprise one or more of a number of different materials, including for example foil of aluminum, copper or stainless steel, or a composite metallized paper or foil structure wherein aluminum, zinc, or other vaporizable metal is vapor deposited upon one or both surfaces of the substrate. Dielectric spacers l3 and 14 generally comprise paper and/or polymeric film as hereinbefore described. More specifically, the dielectric spacer l3 and the metallic electrodes 11 and I2 taken together comprise a capacitor element structure. The dielectric spacer materials, and the voids within and between the spacer materials and the electrodes are impregnated with a dielectric fluid composition.

Referring now to FIG. 2, there is shown an assembled capacitor unit 18 in which is encased a convolutely wound capacitor of the type shown in FIG. 1. The assembled unit includes a container 19, a hermetically sealed cover 20 which includes a small dielectric fluid fill hole 21 and a pair of terminals 22 and 23 projecting through cover 20 and insulated therefrom. Within the container 19 terminals 22 and 23 are connected to terminal connectors 15 and 16 shown in FIG. 1. Although not illustrated, the unit 18 shown in FIG. 2 further includes the dielectric fluid composition which occupies the remaining space in container 19 not occupied by the capacitor element and which also impregnates the dielectric spacers l3 and 14.

The impregnation of the capacitor is accomplished by using conventional procedures. For example, in one general impregnation method, capacitor units encased in assemblies such as capacitor 18 of FIG. 2 are dried under vacuum to remove residual moisture. The drying temperature will vary depending upon the length of the drying cycle but usually ranges from about 60 to C. With too low a temperature, the drying period is excessively long while too high temperature may cause decomposition of the paper or shrinkage of the polymeric film utilized as the dielectric spacer. Hole 21 permits moisture to vent from the interior of container 19 during the drying process.

The impregnating dielectric liquid is admitted to the capacitor assembly through hole 21 preferably while the dried assembly is still under vacuum in a suitable evacuated enclosure. The capacitor element in the con tainer must be submerged by the impregnating liquid and usually enough of the impregnating liquid is introduced to completely flood the container and displace all the air therein. The pressure of the enclosure is then raised to atmospheric pressure and the assembly permitted to stand or soak for a number of hours for thorough penetration of the liquid impregnant. After impregnation the capacitor unit may be sealed by applying a quantity of a suitable solder to hole 21 or by other suitable means. The capacitor assembly may thereafter be subjected to an elevated temperature to increase pressure within the capacitor assembly and aid the impregnation process. Heat and pressure may enhance impregnability by changing the relative wettability, viscosity and solubility of materials. In addition, expansion and contraction of individual components of the system which may be the result of heat and pressure may act as a driving force to induce migration of the liquid into the interstices of the dielectric spacer material.

Several capacitors of the type illustrated in FIGS. 1 and 2 were constructed of aluminum foil and paper separators and were impregnated according to the foregoing description with a dielectric composition comprising a 50/50 mixture of n-butyl-o-chlorophenyl ether and n-butyl-2,4-dichlorophenyl ether containing 0.3 percent 3 ,4-epoxycyclohexylmethyl-3 ,4- epoxycyclohexane carboxylate. A group of eight of these capacitors, designated Test Capacitors, were subjected to service and life tests. The results of these tests were compared to those obtained with a like group of identical capacitors impregnated in a like manner with an electrical grade polychlorinated biphenyl containing about 42 percent chlorine, designated as Control Capacitors. Test data is given in Table l.

atoms, each X is individually chlorine, fluorine or bromine, and n is l or 2.

2. An electrical capacitor comprising at least two electrodes and a solid insulating dielectric sheet posi- TABLE I.-PAPER INSULATED CAPACITO RS* Temp, C c- 22 70 70 70 70 80 00 100 Lilo test conditions Voltage 600 870 900 030 J60 1, 000 1, 000 1, 000 1, 000 Time. hrs 0 744 168 168 120 168 168 168 168 Tan 00372 00340 00341 00338 00311 00330 0035-1 00363 00410 Test capacitors, 8 units {Capocitance, fd. 2. 100 h 094 2. 005 2. 005 2. 001 2. 001 2. 081 2. 0M 2. 053 No. of failures 0 0 0 0 0 0 0 0 0 Tan 00345 00315 00317 .00316 00305 00307 00315 00343 00404 Control capacitors. 8 units "{Capacitanoe, pf 1. 070 1. 88!) 1.888 1. 888 1. 886 1. 884 1. 870 1. 863 1. 854 No of failures 0 0 0 0 2 O 0 0 2 Two sheets of 0.66 mil. Kraft paper.

with a dielectric liquid composition comprising mixed halogenated aliphatic-aromatic ethers represented by the structure wherein R is an alkyl of from one to about 10 carbon tioned therebetween, the interstices between said dielectric sheet and said electrodes being impregnated with a dielectric liquid composition comprising a mixture of n-butyl-o-chlorophenyl ether and n-butyl-2,4- dichlorophenyl ether in a ratio of from about 1:4 to about 4:1.

3. An electrical capacitor comprising at least two electrodes and a solid insulating dielectric sheet positioned therebetween, the interstices between said dielectric sheet and said electrodes being impregnated with a dielectric liquid composition comprising a mixture of n-butyl-o-chlorophenyl ether and n-butyl-2,4- dichlorophenyl ether in a ratio of from about 1:4 to about 4:1 and from about 0.l to 3 percent by weight of 3 ,4-epoxycyclohexylmethyl-3 ,4-epoxycyclohexane carboxylate. 

2. An electrical capacitor comprising at least two electrodes and a solid insulating dielectric sheet positioned therebetween, the interstices between said dielectric sheet and said electrodes being impregnated with a dielectric liquid composition comprising a mixture of n-butyl-o-chlorophenyl ether and n-butyl-2,4-dichlorophenyl ether in a ratio of from about 1:4 to about 4:1.
 3. An electrical capacitor comprising at least two electrodes and a solid insulating dielectric sheet positioned therebetween, the interstices between said dielectric sheet and said electrodes being impregnated with a dielectric liquid composition comprising a mixture of n-butyl-o-chlorophenyl ether and n-butyl-2,4-dichlorophenyl ether in a ratio of from about 1:4 to about 4:1 and from about 0.1 to 3 percent by weight of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate. 